2.2]decane Main and defining the geometry from the exocyclic double bond. The activation energies of development of your vinyl-gold intermediates were being calculated and exposed a silyl enol ether with the unprotected indole moiety as an appropriate precursor for that Toste cyclization. This six-stage synthesis didn't require any nonstrategic red

2.two]decane Main and defining the geometry of your exocyclic double bond. The activation energies of formation in the vinyl-gold intermediates ended up calculated and exposed a silyl enol ether with an unprotected indole moiety as an appropriate precursor for your Toste cyclization. This 6-step synthesis did not include any nonstrategic redox mani

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